The atomic arrangement within the mean elastic free path
is resolved by the electrons at the Fermi surface employing the concept of
planes and cubes.
Hence, the volume per atom is a cube of the side length
and the average interplanar distance is
.
Take such a stack of atomic planes which are perpendicular to
a direction say
.
Then, the condition for constructive interference of
the scattered waves
emerging from the incident wave
reads as
=
where
=
is the momentum transfer.
We are interested in transitions with
=
=
and normal vectors
which
correspond to the supposed macroscopic isotropy of the system.
This means that any three directions which are mutually
perpendicular to one another have to be fully equivalent.
Hence, an "interference cube" (fig.1a)
which is concentric with the Fermi sphere
helps visualizing the interference conditions for scattering
between states at the Fermi surface.
According to the interference condition mentioned above,
transitions from
to
are accompanied by constructive
interference the more the closer components of
are approaching the side length of the interference cube,
.
This makes the difference to the Brillouin zone
of a cubical crystal where extinction results from any misfit to the exact
Bragg conditions.